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Re: Winding Secondary



Tesla List wrote:
> 
> > Subject: Re: Winding Secondary
> 
> >From major-at-vicksburg-dot-comTue Aug 13 20:55:44 1996
> Date: Tue, 13 Aug 1996 20:39:00 -0500
> From: RODERICK MAXWELL <major-at-vicksburg-dot-com>
> To: tesla-at-pupman-dot-com
> Subject: Re: Winding Secondary
> 
> Tesla List wrote:
>Do you have to prepare polystyrene?

Roderick:
	I believe that the material that has demanded the most prep work is
PVC, specifically the PVC sewer/drain type pipe that is readily
available.  I've learned from previous postings that it will absorb
moisture and cause the secondary to break down quickly.  After 10 months
of reading posts, I have never seen a comment made as far as pre-coating
a polystyrene form.  I got some very good help over the last few months
and shown below is a copy of some information that was posted last fall
on plastics.  I hope this is of some interest to you.

Chuck Curran


Subject: 
            Dielectric Tables
       Date: 
            Mon, 27 Nov 1995 00:54:00 GMT
       From: 
            richard.quick-at-slug-dot-org (Richard Quick)
Organization: 
            St. Louis Users Group
         To: 
            ccurran-at-earth.execpc-dot-com


As you go out and start looking at materials for use in a new 
Tesla coil system, you might want to review the tables below on 
plastics and other insulators/dielectrics.

Look for plastics with low RF dissipation factors when you are 
shopping for coil construction materials. Most of the common 
plastics will be found in the tables below:

update 8/1/1995
Compiled by Ed Harris 
174 W 18th Ave
Columbus, OH 43210
New inclusions to the old stuff:
Info on magnet wire coatings!

>From all the discussion on this group about building ones own capacitors 
and what types of materials make good coil forms, I became interested in 
obtaining some hard (or semi-hard) data on different types of polymers.
I 
was also interested when someone (?) asked whether ABS was a good
material 
for coil forms - I had no idea. It seems that it is much preferable to
PVC.

I thought I'd share the results of my library searches:

First, I'd like to list some of the plastics with their chemical name
and 
their abreviations. Trade names are listed if they are well known.

chemical name                   abreviation     aka             notes
-------------                   -----------     ---             ------
polyethylene                    PE              polythene-British!

                                                        CH2-CH2 monomer

                                HDPE                    High density PE
                                LDPE                    Low density PE

polypropylene                   PP                      replace one H in
PE
                                                        by CH3

polyvinyl chloride              PVC                     replace one H in
PE
                                                        by one Cl atom

polyvinylidene chloride         CPVC PVDC               replace two H in
PE
                                                        by two Cl

polystyrene                     PS                      replace H in PE
by
                                                        a benzene ring

polyvinyl flouride              PVF                     replace H in PE
by
                                                        F atom

polyvinylidene flouride         PVDF            Kynar   repace two H in
PE 
                                                        by two F atoms
                                                        *wire wrap
insul.

polymethyl methacrylate         PMMA            Plexiglas
                                                Lucite
                                                Perspex (British)

polytetraflouroethylene         PTFE            Teflon  replace all H in
PE
                                                        by F atoms

polychlorotrifloroethylene      PCTFE           Kel-F   replace 3 H in
PE
                                                        with F one with
Cl

polyamide 6                     PA 6            Nylon 6

polyamide 66                    PA 66           Nylon 66

polyamide-imide                 PAI             Torlon

polyurethane                    PUR

polycarbonate                   PC              Lexan

Polyacetal                      POM             Delrin

polyethlene terephthalate       PET             Mylar   co-polymer of PE

cellulose actetate butyrate     CAB             Butyrate

cellulose nitrate               CN              "Laquer" *typical
constituent
                                                        laquers 

acrylonitrile-butadiene-styrene ABS             Cycopac ter-polymer of 
                                                        polystyrene
                                                * warning Jim Oliver
says
                                                this name may apply to
                                                may many diff materials

polyimide                       PI              Kapton

polyvinyl formal                ?               Formvar wire coating

OK, there are zillions of others, but these are the ones I picked
because I 
heard of them before...
A couple of comments: Notice that there are many polymers which share a 
common structure with polyethylene, all that changes is replacing one or 
more of the H atoms in (PE) with some other atom or group of atoms. Then 
there are plastics which are called co-polymers or ter-polymers. A co-
polymer is just taking two different monomers and sticking them together
in 
a unit cell before polymerizing. Example: PET. Likewsie, a ter-polymer
is 
just sticking three monomers into a unit cell and then polymerizing. A
very 
common example is ABS which is used as sewar and drainage pipe.


Now for the useful stuff. What are the electrical properties of some of 
these polymers? The most useful properties in my mind are the dielectric 
constant (or permittivity), the dielectric strenght, and the dissipation 
factor. All of these properties are dependent on temperature and
frequency, 
but amazingly they also depend somewhat on the actual thickness of the 
material (as in thin films).

----A couple of notes:
All three properties mentioned above depend on frequency, but it turns
out 
that for many non-polar polymers (ie PE) that the dielectric constant
and 
dissipation factor do not depend much on frequency. I'll show some data
for 
some of the plastics I could find. However, nobody seems to have data on 
the frequency dependence of the dielectric strength. It is best just to 
assume that this was done at DC.

One property which is not well known for polymers is that the breakdown 
electric field or dielectric strength (VOLTS/INCH etc...) depends on the 
actual thickness of the film. Typically, as the film gets thinner, the 
dielectric strength goes up!!! For example, LDPE has a strength of
800volts 
per mil at 80 mils, but this goes up to 1400volts/mil at 20mils!! 
Polystyrene exceeds even this! I have personally done measurements on
LDPE
which show DC breakdowns of 3000Volts/mil at 2mils... 

Finally what is dissipation factor? It is a measure of how lossy the 
material is to alternating electric fields (as in Tesla coils and tank 
capacitors). It is defined by 

        Ir
        --- = tangent (delta)   = DF
        Ic

where Ir is the resistive or dissipative current and Ic is the
capacitive 
or displacement or reactive current. Delta is the phase angle between 
these currents  (in the complex plane). Another expression which
contains 
the same information is the Power Factor. For those familiar with this
term 
they are related by:

        PF=DF/SQRT(1+DF^2)

For small DF, then PF is approximately equal to DF. Obvisously, one
would 
like to have DF as small as possible for low loss, high Q systems. In
fact, 
for the purposes of approximation, the Q of a capacitor with low DF or
PF 
is simply Q=1/DF=1/PF

Absolute power lost in the system is:
1. goes up with the square of the voltage gradient (electric field)
2. goes up linearly with the volume of the dielectric in the field
   ( make your coil forms thin)
3. goes up linearly with increasing dielectric constant
   ( don't use barium titanate primary caps!)
4. generally increases with frequency


polymer         dielectric      dielectric      dissipation
                constant        strength        factor
                50Hz / 1Mhz     (Kv/cm)         50Hz / 1Mhz (x10^-3)
--------        -----------     -----------     -----------
LDPE            2.29 / 2.28     370             .15 / .08
HDPE            2.35 / 2.34     --              .24 / .20
PP              2.27 / 2.25     240             .40 / .50
PVC-plasticized 4-8  / 4-5      270             80  / 120
PS              2.5  / 2.5      200-300         .1-.4/.05-.4
ABS             2.4-5/2.4-3.8   ~400            3-8 / 2-15
PMMA            3.3-3.9/2.2-3.2 140             40-60/4-40
POM             3.7 / 3.7       400             5 / 5
PTFE            2.1  / 2.1      480             .2 / .2
PCTFE           2.3-2.8/2.3-2.5 550             1 / 20
PA-6            3.8 / 3.4       400             10 / 30
PA-66           8 / 4           600             140 / 80
PC              3.0 / 2.9       380             .7 / 10
PET             4.0 / 4.0       420             2 / 20
PI              3.5 / 3.4       560             2 / 5
PUR-linear      5.8 / 4.0       >300            120 / 70
PUR-thermoset   3.6 / 3.4       240             50 / 50
PUR-thermoplas  6.6 / 5.6       300             30 / 60
CAB             3.7 / 3.5       400             6 / 21
Silicone        3.6             200             5-13 / 7        


Another comparison:

polymer         Dielectric constant / Dissipation Factor (x10^-3)

                100 Hz          1000 Hz         1 Mhz           10 Mhz

ABS             2.8/5           2.8/6           2.8/8           2.8/7
PMMA            3.6/62          3.2/58          3.1/40          2.9/33
PC              3.1/1           3.1/1.3         3.1/7           3.1/11
PE              2.3/.1          2.3/.1          2.3/.1          2.3/.1
PA-6            4.2/31          3.8/24          3.8/31          4.0/20

**************************************************************************
Magnet wire coatings from Phelps-Dodge:
All data pertain to 18 gauge magnet wires
Build= thickness of coating

Coating                 What's it made of       Build           DC 
----------              -----------------       -----          
breakdown

Thermaleze-T (TZT)      polyester-imide         2.8mils         11kV

Armored Polythemaleze                           3.05mils        11kV
(APTZ)                  modified polyester&
                        modified polyamide-imide

Imideze (ML)            Aromatic polyimide      2.9mils         12kV

Formvar                 modified polyviynyl     3.0mils         10kV
                        formal                  

Sodereze                modified polyurethane   2.9mils         8.5kV

Nyleze                  Polyurethane            2.9mils         8.5kV 
                        & polyamide

* Note: for the dielectric breakdown - These numbers are much bigger
than 
for bulk materials because they are very thin coatings. As mentioned 
previously, the breakdown field increases as the thickness goes down.
{a similar effect happens in gases and liquids and was studied by
Paschen}

Anyway, here's the dielectric constant/DF numbers for these matearials:

Material                Dielectric Const. / DF x 10^-3

                1kHz            100kHz          1Mhz            rating
TZT             3.7/5.6         3.56/16.4       3.58/21.5       3rd

APTZ            3.86/6.9        3.69/22.1       3.67/26.6       5th

ML              3.34/0.9        3.3/5.7         3.36/9.8        2nd to 
                                                                teflon

Formvar*        3.6/11.2        3.41/25.2       3.37/28.4       5th

Soldereze       3.85/11.3       3.66/20.7       3.66/23.1       4th

Nyleze          4.07/19.7       3.78/27.1       3.75/27.2       6th

* This shows that Formvar is far from an ideal coating for magnet wire
used in Tesla Coils when compared to something like Polyimide coatings


References:
1. Polymer Engineering Principles, Richard C. Progelhof and James Throne
2. Plastics for Electronics, Martin T. Goosey
3. Handbook of Plastics in Electronics, Dan Grzegorczyk and George
Feineman
4. SPI Plastics Engineering Handbook, Society of the Plasitics Industry
5. Electrical Engineer's Handbook, Pender - 4th Edition
6. Phelps-Dodge magnet wire product data

Plastics sources: probably best to check your local distributors, but
there 
is a mail order company called US Plastic Corp -at-800-537-9724 (catalog). 
They have rod/sheet/tubing of PVC, PMMA, CAB, POM, PE, PS. Of
particlular 
note:
        Butyrate tubing up to 6 " diameter * lower loss coil forms
        Polystyrene tubing to 4 " dia * very low loss coil form
        4x8ft LDPE sheet 60mil or other * Capacitors


... If all else fails... Throw another megavolt across it!
___ Blue Wave/QWK v2.12